以吡啶、喹啉和吲哚为单一碳源时反硝化过程中亚硝酸盐积累及动力学研究

白凡玉, 岳秀萍, 段燕青, 张婧. 以吡啶、喹啉和吲哚为单一碳源时反硝化过程中亚硝酸盐积累及动力学研究[J]. 环境工程学报, 2015, 9(2): 665-669. doi: 10.12030/j.cjee.20150226
引用本文: 白凡玉, 岳秀萍, 段燕青, 张婧. 以吡啶、喹啉和吲哚为单一碳源时反硝化过程中亚硝酸盐积累及动力学研究[J]. 环境工程学报, 2015, 9(2): 665-669. doi: 10.12030/j.cjee.20150226
Bai Fanyu, Yue Xiuping, Duan Yanqing, Zhang Jing. Nitrite accumulation and kinetic study of denitrification with pyridine, quinoline and indole as sole carbon source[J]. Chinese Journal of Environmental Engineering, 2015, 9(2): 665-669. doi: 10.12030/j.cjee.20150226
Citation: Bai Fanyu, Yue Xiuping, Duan Yanqing, Zhang Jing. Nitrite accumulation and kinetic study of denitrification with pyridine, quinoline and indole as sole carbon source[J]. Chinese Journal of Environmental Engineering, 2015, 9(2): 665-669. doi: 10.12030/j.cjee.20150226

以吡啶、喹啉和吲哚为单一碳源时反硝化过程中亚硝酸盐积累及动力学研究

  • 基金项目:

    国家自然科学基金资助项目(51378330)

    山西省科技攻关项目(20120311008-1)

  • 中图分类号: X703

Nitrite accumulation and kinetic study of denitrification with pyridine, quinoline and indole as sole carbon source

  • Fund Project:
  • 摘要: 以吡啶、喹啉和吲哚为单一碳源,通过摇床实验进行反硝化过程动力学研究。实验结果表明,以吡啶和喹啉为单一碳源的反硝化过程中,NO2--N的积累率分别达到了53.4%和16.4%;以吲哚为单一碳源的反硝化过程中,NO2--N的积累现象不明显,最高不超过4%。以NO3--N+0.6 NO2--N作为反硝化电子受体,采用基于Monod 方程的动态模型进行拟合, 拟合曲线与实验测定值相关性良好。其次,采用基于Monod 方程的微分方程组模型,也能够很好地拟合3种碳源条件下反硝化过程硝酸盐、亚硝酸盐质量浓度的变化,得到相应的动力学参数。
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  • [1] Jori A., Calamari D., Cattabeni F., et al. Ecotoxicological profile of pyridine: Working party on ecotoxicological profiles of chemicals. Ecotoxicology and Environmental Safety, 1983, 7(3): 251-275
    [2] Sideropoulos A. S., Specht S. M. Evaluation of microbial testing methods for the mutagenicity of quinoline and its derivatives. Current Microbiology, 1984, 11(2): 59-65
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    [5] 李咏梅,顾国维,赵建夫.焦化废水中几种含氮杂环化合物缺氧降解机理. 同济大学学报,2001,29(6):720-723 Li Y. M., Gu G. W., Zhao J. F. Study on anoxic biodegradation mechanism of several nitrogen heterocyclic compounds in coal coking wastewater. Journal of Tongji University, 2001, 29(6): 720-723(in Chinese)
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    [9] Gu J. D., Fan Y., Shi H. Relationship between structures of substituted indolic compounds and their degradation by marine anaerobic microorganisms. Marine Pollution Bulletin, 2002, 45(1): 379-384
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    [11] 杜宪,岳秀萍,王孝维,等.厌氧复合床处理模拟焦化废水的反硝化动力学研究.化工学报,2013,64(7):2650-2655 Du X., Yue X. P., Wang X. W.,et al. Denitrification dynamics of treating analog coking wastewater in upflow blanket filter. CIESC Journal, 2013,64(7): 2650-2655(in Chinese)
    [12] 李亚新,赵晨红.紫外分光光度法测定焦化废水的主要污染物.中国给水排水,2001,17(1):54-56 Li Y. X.,Zhao C. H. Ultraviolet spectrophotometric determination of main pollutants of coking wastewater. China Water & Wastewater,2001,17(1):54-56(in Chinese)
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出版历程
  • 收稿日期:  2014-01-26
  • 刊出日期:  2015-02-07
白凡玉, 岳秀萍, 段燕青, 张婧. 以吡啶、喹啉和吲哚为单一碳源时反硝化过程中亚硝酸盐积累及动力学研究[J]. 环境工程学报, 2015, 9(2): 665-669. doi: 10.12030/j.cjee.20150226
引用本文: 白凡玉, 岳秀萍, 段燕青, 张婧. 以吡啶、喹啉和吲哚为单一碳源时反硝化过程中亚硝酸盐积累及动力学研究[J]. 环境工程学报, 2015, 9(2): 665-669. doi: 10.12030/j.cjee.20150226
Bai Fanyu, Yue Xiuping, Duan Yanqing, Zhang Jing. Nitrite accumulation and kinetic study of denitrification with pyridine, quinoline and indole as sole carbon source[J]. Chinese Journal of Environmental Engineering, 2015, 9(2): 665-669. doi: 10.12030/j.cjee.20150226
Citation: Bai Fanyu, Yue Xiuping, Duan Yanqing, Zhang Jing. Nitrite accumulation and kinetic study of denitrification with pyridine, quinoline and indole as sole carbon source[J]. Chinese Journal of Environmental Engineering, 2015, 9(2): 665-669. doi: 10.12030/j.cjee.20150226

以吡啶、喹啉和吲哚为单一碳源时反硝化过程中亚硝酸盐积累及动力学研究

  • 1. 太原理工大学环境科学与工程学院, 太原 030024
基金项目:

国家自然科学基金资助项目(51378330)

山西省科技攻关项目(20120311008-1)

摘要: 以吡啶、喹啉和吲哚为单一碳源,通过摇床实验进行反硝化过程动力学研究。实验结果表明,以吡啶和喹啉为单一碳源的反硝化过程中,NO2--N的积累率分别达到了53.4%和16.4%;以吲哚为单一碳源的反硝化过程中,NO2--N的积累现象不明显,最高不超过4%。以NO3--N+0.6 NO2--N作为反硝化电子受体,采用基于Monod 方程的动态模型进行拟合, 拟合曲线与实验测定值相关性良好。其次,采用基于Monod 方程的微分方程组模型,也能够很好地拟合3种碳源条件下反硝化过程硝酸盐、亚硝酸盐质量浓度的变化,得到相应的动力学参数。

English Abstract

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