天津市地表水体与沉积物中7种高关注酚类化合物的污染特征与生态风险分析

殷伟, 范德玲, 汪贞, 古文, 周林军, 刘济宁, 王冬梅, 石利利. 天津市地表水体与沉积物中7种高关注酚类化合物的污染特征与生态风险分析[J]. 生态毒理学报, 2020, 15(1): 230-241. doi: 10.7524/AJE.1673-5897.20190125002
引用本文: 殷伟, 范德玲, 汪贞, 古文, 周林军, 刘济宁, 王冬梅, 石利利. 天津市地表水体与沉积物中7种高关注酚类化合物的污染特征与生态风险分析[J]. 生态毒理学报, 2020, 15(1): 230-241. doi: 10.7524/AJE.1673-5897.20190125002
Yin Wei, Fan Deling, Wang Zhen, Gu Wen, Zhou Linjun, Liu Jining, Wang Dongmei, Shi Lili. Pollution Characteristics and Ecological Risks of 7 Phenolic Compounds of High Concern in the Surface Water and Sediments of Tianjin, China[J]. Asian Journal of Ecotoxicology, 2020, 15(1): 230-241. doi: 10.7524/AJE.1673-5897.20190125002
Citation: Yin Wei, Fan Deling, Wang Zhen, Gu Wen, Zhou Linjun, Liu Jining, Wang Dongmei, Shi Lili. Pollution Characteristics and Ecological Risks of 7 Phenolic Compounds of High Concern in the Surface Water and Sediments of Tianjin, China[J]. Asian Journal of Ecotoxicology, 2020, 15(1): 230-241. doi: 10.7524/AJE.1673-5897.20190125002

天津市地表水体与沉积物中7种高关注酚类化合物的污染特征与生态风险分析

    作者简介: 殷伟(1992-),女,硕士,研究方向为化学品风险评估,E-mail:18761800167@163.com
  • 基金项目:

    国家重点研发计划项目(2018YFC1801601)

  • 中图分类号: X171.5

Pollution Characteristics and Ecological Risks of 7 Phenolic Compounds of High Concern in the Surface Water and Sediments of Tianjin, China

  • Fund Project:
  • 摘要: 为探究地表水体与沉积物中酚类化合物的污染分布特征和生态风险,选择天津市3个水源地与6条主要河流,采集了26个地表水样与6个沉积物样品,利用固相萃取与超声萃取、高效液相色谱-串联质谱法(HPLC-MS/MS)测定了水样及沉积物中1-萘酚(1-naphthol)、壬基酚(nonylphenol, NP)、双酚A(bisphenol A, BPA)、2-苯基苯酚(biphenyl-2-ol)、3,4-二氯酚(3,4-dichlorophenol)、四溴双酚A(tetrabromobisphenol A, TBBPA)和对叔丁基苯酚(p-tert-butylphenol, PTBP)等7种高关注酚类化合物的浓度水平,并应用物种敏感性分布(species sensitivity distribution, SSD)法和熵值法(ecological risk quotient, RQ)评估7种酚类化合物水环境和沉积物的生态风险。结果表明,地表水样中7种酚类化合物均全部检出;其中壬基酚的检出浓度最高,其次为四溴双酚A、对叔丁基苯酚、1-萘酚、2-苯基苯酚、3,4-二氯酚和双酚A。沉积物中酚类化合物的污染分布规律与水样相似,除双酚A外的目标物全部检出。其中,壬基酚浓度比其他物质浓度高2个数量级。风险评估结果显示,壬基酚对水环境与沉积物存在不可接受的风险;而四溴双酚A、对叔丁基苯酚、1-萘酚、2-苯基苯酚、3,4-二氯酚和双酚A则对环境具有较低风险或者存在一定的风险。
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天津市地表水体与沉积物中7种高关注酚类化合物的污染特征与生态风险分析

    作者简介: 殷伟(1992-),女,硕士,研究方向为化学品风险评估,E-mail:18761800167@163.com
  • 1. 南京信息工程大学环境科学与工程学院, 南京 210044;
  • 2. 生态环境部南京环境科学研究所, 南京210042;
  • 3. 天津市固体废物及有毒化学品管理中心, 天津 300191
基金项目:

国家重点研发计划项目(2018YFC1801601)

摘要: 为探究地表水体与沉积物中酚类化合物的污染分布特征和生态风险,选择天津市3个水源地与6条主要河流,采集了26个地表水样与6个沉积物样品,利用固相萃取与超声萃取、高效液相色谱-串联质谱法(HPLC-MS/MS)测定了水样及沉积物中1-萘酚(1-naphthol)、壬基酚(nonylphenol, NP)、双酚A(bisphenol A, BPA)、2-苯基苯酚(biphenyl-2-ol)、3,4-二氯酚(3,4-dichlorophenol)、四溴双酚A(tetrabromobisphenol A, TBBPA)和对叔丁基苯酚(p-tert-butylphenol, PTBP)等7种高关注酚类化合物的浓度水平,并应用物种敏感性分布(species sensitivity distribution, SSD)法和熵值法(ecological risk quotient, RQ)评估7种酚类化合物水环境和沉积物的生态风险。结果表明,地表水样中7种酚类化合物均全部检出;其中壬基酚的检出浓度最高,其次为四溴双酚A、对叔丁基苯酚、1-萘酚、2-苯基苯酚、3,4-二氯酚和双酚A。沉积物中酚类化合物的污染分布规律与水样相似,除双酚A外的目标物全部检出。其中,壬基酚浓度比其他物质浓度高2个数量级。风险评估结果显示,壬基酚对水环境与沉积物存在不可接受的风险;而四溴双酚A、对叔丁基苯酚、1-萘酚、2-苯基苯酚、3,4-二氯酚和双酚A则对环境具有较低风险或者存在一定的风险。

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